The Volunteer State, nickname for Tennessee
Volunteer, North Carolina
Volunteer Island, also called Starbuck Island, among the Line Islands of Kiribati
Volunteer Park (Seattle)
Volunteer Hotel, Balmain - former pub in Balmain, Sydney, Australia
Volunteer State Community College - community college located in Gallatin, Tennessee
Volunteer Canteen - pub in Liverpool, England
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Volunteers (album), a 1969 album by Jefferson Airplane
Volunteers (film) a 1985 comedy film starting Tom Hanks
List of VFDs - "V.F.D." acronym in A Series of Unfortunate Events by Lemony Snicket, with several meanings involving "Volunteer".
Volunteer (band) - Ukrainian punk/metal band
Volunteer Jam - annual Charlie Daniels Band concert in Nashville, Tennessee.